183 research outputs found
Strong correlation effects and optical conductivity in electron doped cuprates
We demonstrate that most features ascribed to strong correlation effects in
various spectroscopies of the cuprates are captured by a calculation of the
self-energy incorporating effects of spin and charge fluctuations. The self
energy is calculated over the full doping range of electron-doped cuprates from
half filling to the overdoped system. The spectral function reveals four
subbands, two widely split incoherent bands representing the remnant of the
split Hubbard bands, and two additional coherent, spin- and charge-dressed
in-gap bands split by a spin-density wave, which collapses in the overdoped
regime. The incoherent features persist to high doping, producing a remnant
Mott gap in the optical spectra, while transitions between the in-gap states
lead to pseudogap features in the mid-infrared.Comment: 5 pages, 4 figure
Cu -edge Resonant Inelastic X-Ray Scattering in Edge-Sharing Cuprates
We present calculations for resonant inelastic x-ray scattering (RIXS) in
edge-shared copper oxide systems, such as CuGeO and LiCuO,
appropriate for hard x-ray scattering where the photoexcited electron lies
above oxygen 2p and copper 3d orbital energies. We perform exact
diagonalizations of the multi-band Hubbard and determine the energies, orbital
character and resonance profiles of excitations which can be probed via RIXS.
We find excellent agreement with recent results on LiCuO and
CuGeO in the 2-7 eV photon energy loss range.Comment: Updated with new data, expanded 9 pages, 9 figure
Phonon dispersion and low energy anomaly in CaC
We report measurements of phonon dispersion in CaC using inelastic X-ray
and neutron scattering. We find good overall agreement, particularly in the 50
meV energy region, between experimental data and first-principles
density-functional-theory calculations. However, on the longitudinal dispersion
along the axis of the rhombohedral representation, we find an
unexpected anti-crossing with an additional longitudinal mode, at about 11 meV.
At a comparable energy, we observe also unexpected intensity on the in-plane
direction. These results resolve the previous incorrect assignment of a
longitudinal phonon mode to a transverse mode in the same energy range. By
calculating the electron susceptibility from first principles we show that this
longitudinal excitation is unlikely to be due to a plasmon and consequently can
probably be due to defects or vacancies present in the sample.Comment: Accepted for publication in Physical Review
Investigation of the Impact of Hydrolytically Cleavable Groups on the Stability of Poly(ethylene glycol) Based Hydrogels Cross-Linked via the Inverse Electron Demand Diels-Alder (iEDDA) Reaction
Eight-armed poly(ethylene glycol) (PEG) hydrogels cross-linked via inverse electron demand Diels–Alder reaction between norbornene and tetrazine groups are promising materials for long-term protein delivery. While a controlled release over 265 days is achieved for 15% w/v hydrogels in the previous study, the material shows high stability over 500 days despite having cleavable ester linkages between the PEG macromonomers and their functionalities. In this study, the hydrolyzable ester linkers in the PEG-norbornene precursor structure are exchanged to reduce the degradation time. To this end, 3,6-epoxy-1,2,3,6-tetrahydrophthalimide, phenyl carbamate, carbonate ester, and phenyl carbonate ester are introduced as degradable functional groups. Oscillatory shear experiments reveal that they are not affected the in situ gelation. All hydrogel types have gel points of less than 20 s even at a low polymer concentration of 5% w/v. Hydrogels with varying polymer concentrations have similar mesh sizes, all of which fell in the range of 4–12 nm. The inclusion of phenyl carbonate ester accelerates degradation considerably, with complete dissolution of 15% w/v hydrogels after 302 days of incubation in phosphate buffer (pH 7.4). Controlled release of 150 kDa fluorescein isothiocyanate-dextran over a period of at least 150 days is achieved with 15% w/v hydrogels
Sharp optical phonon softening close to optimal doping in LaBaCuO
We report a direct observation of a sharp Kohn-like anomaly in the doubly
degenerate copper-oxygen bond-stretching phonon mode occurring at
in LaBaCuO with
, thanks to the high resolution of
inelastic x-ray scattering. This anomaly is clearly seen when the inelastic
signal is analysed using a single mode but is also consistent with a two mode
hypothesis possibly due to a splitting of the degenerate modes due to symmetry
breaking stripes. Our observation shows that the effect persists at the stripe
propagation vector in a superconducting system close to optimal doping
Authenticity and Communication
Authenticity is not an absolute and constant quality inherent in an object or
an experience; it is constructed in the process of research. Actors inscribe
and attribute it to both material objects and subjective processes like
communication and consumption. This article from the research group seeks on
the one hand to reflect on the historical scope of action and action patterns
among actors from various disciplines between the conflicting priorities of
authentication and communication, and on the other to find ways to visualize
and operationalize attribution processes through joint reflection. When we
look at both history and the discussions fifty years after the Venice Charter,
its idea to hand on historic monuments “in the full richness of their
authenticity” has turned into an abundance of vibrant action and decision-
making
Tremendous bleeding complication after vacuum-assisted sternal closure
Vacuum-assisted closure (VAC) of complex infected wounds has recently gained popularity among various surgical specialties. The system is based on the application of negative pressure by controlled suction to the wound surface. The effectiveness of the VAC System on microcirculation and the promotion of granulation tissue proliferation are proved. No contraindications for the use in deep sternal wounds in cardiac surgery are described. In our case report we illustrate a scenario were a patient developed severe bleeding from the ascending aorta by penetration of wire fragments in the vessel. We conclude that all free particles in the sternum have to be removed completely before negative pressure is used
Dispersive charge density wave excitations and temperature dependent commensuration in Bi2Sr2CaCu2O8+{\delta}
Experimental evidence on high-Tc cuprates reveals ubiquitous charge density
wave (CDW) modulations, which coexist with superconductivity. Although the CDW
had been predicted by theory, important questions remain about the extent to
which the CDW influences lattice and charge degrees of freedom and its
characteristics as functions of doping and temperature. These questions are
intimately connected to the origin of the CDW and its relation to the
mysterious cuprate pseudogap. Here, we use ultrahigh resolution resonant
inelastic x-ray scattering (RIXS) to reveal new CDW character in underdoped
Bi2Sr2CaCu2O8+{\delta} (Bi2212). At low temperature, we observe dispersive
excitations from an incommensurate CDW that induces anomalously enhanced phonon
intensity, unseen using other techniques. Near the pseudogap temperature T*,
the CDW persists, but the associated excitations significantly weaken and the
CDW wavevector shifts, becoming nearly commensurate with a periodicity of four
lattice constants. The dispersive CDW excitations, phonon anomaly, and
temperature dependent commensuration provide a comprehensive momentum space
picture of complex CDW behavior and point to a closer relationship with the
pseudogap state
Dentinal hypersensitivity: a review
The document attached has been archived with permission from the Australian Dental Association. An external link to the publisher’s copy is included.Tooth sensitivity is a very common clinical presentation which can cause considerable concern for patients. This condition is frequently encountered by periodontists, dentists, hygienists and dental therapists. The management of this condition requires a good understanding of the complexity of the problem, as well as the variety of treatments available. This review considers the aetiology, incidence and management of dentinal hypersensitivity.PM Bartol
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